7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan

نویسندگان

  • Hong Dae Choi
  • Pil Ja Seo
  • Byung Ki Kim
  • Byeng Wha Son
  • Uk Lee
چکیده

In the title compound, C(24)H(14)BrClOS, the S-bound 4-chloro-phenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal structure is stabilized by aromatic π-π inter-actions between the furan and the central benzene rings of the neighbouring naphthofuran fragments, and between the outer benzene rings of the neighbouring naphthofuran fragments; the centroid-centroid distances within the stack are 3.879 (2) and 3.857 (2) Å. In addition, inter-molecular C-Cl⋯π inter-actions [3.505 (2) Å] between the Cl atom and the 2-phenyl ring are present.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2009